AP EAMCET · Chemistry · Alcohols Phenols and Ethers
Consider the following sequence of reactions
Isopropyl benzene \(\xrightarrow{\mathrm{O}_2} x \xrightarrow[\mathrm{H}_2 \mathrm{O}]{\mathrm{H}^{+}}\)
\(+z\)
The incorrect statement about z is
- A z gives yellow precipitate of \(\mathrm{CHI}_3\) with \(\mathrm{NaOH}+\mathrm{I}_2\) solution
- B z gives isopropyl alcohol on reduction with \(\mathrm{H}_2\) in the presence of Pd catalyst
- C z on reaction with \(\mathrm{CH}_3 \mathrm{MgBr}\) followed by hydrolysis gives \(2^{\circ}\) alcohol
- D \(z\) does not give positive test with Fehling's reagent
Answer & Solution
Correct Answer
(C) z on reaction with \(\mathrm{CH}_3 \mathrm{MgBr}\) followed by hydrolysis gives \(2^{\circ}\) alcohol
Step-by-step Solution
Detailed explanation
Isopropyl benzene \( \xrightarrow{\mathrm{O}_2} \) Cumene hydroperoxide (x) Cumene hydroperoxide (x) \( \xrightarrow[\mathrm{H}_2 \mathrm{O}]{\mathrm{H}^{+}} \) Phenol \( + \mathrm{CH}_3 \mathrm{COCH}_3 \) (z) Therefore, \( \mathrm{z} = \mathrm{Acetone} \).…
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