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TS EAMCET · Chemistry · Coordination Compounds

Which one of the following complex ions has geometrical isomers?

  1. A \(\left[\mathrm{Co}(\mathrm{Cl})_2(\mathrm{en})_2\right]^{+}\)
  2. B \(\left[\mathrm{Cr}\left(\mathrm{NH}_3\right)_4(\mathrm{en})\right]^{3+}\)
  3. C \(\left[\mathrm{Co}(\mathrm{en})_3\right]^{3+}\)
  4. D \(\left[\mathrm{Ni}\left(\mathrm{NH}_3\right)_5 \mathrm{Br}\right]^{+}\)
Verified Solution

Answer & Solution

Correct Answer

(A) \(\left[\mathrm{Co}(\mathrm{Cl})_2(\mathrm{en})_2\right]^{+}\)

Step-by-step Solution

Detailed explanation

So, \(\left[\mathrm{Co}(\mathrm{Cl})_2,(\mathrm{en})_2\right]^{+}\)have cis and trans isomers hence it show geometrical isomersism.