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TS EAMCET · Chemistry · Solutions

The observed molar mass determined for \(\mathrm{Na}_2 \mathrm{SO}_4\) by freezing point depression method is \(50.0 \mathrm{~g} / \mathrm{mol}\). The molecular weight of \(\mathrm{Na}_2 \mathrm{SO}_4\) is 142 . What will be the degree of dissociation \(\alpha\) for \(\mathrm{Na}_2 \mathrm{SO}_4\) in water?

  1. A 0.23
  2. B 0.18
  3. C 0.78
  4. D 0.92
Verified Solution

Answer & Solution

Correct Answer

(D) 0.92

Step-by-step Solution

Detailed explanation

van't Hoff factor, \(\begin{aligned} i & =\frac{(\text { Molar mass })_{\text {calculated }}}{(\text { Molar mass })_{\text {observed }}} \\ & =\frac{142}{50}=2.84\end{aligned}\) \(\mathrm{Na}_2 \mathrm{SO}_4\) is an electrolyte in water…