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TS EAMCET · Chemistry · Thermodynamics (C)

The \(\Delta_f \mathrm{H}^{\circ}\) of \(\mathrm{AO}(\mathrm{s}), \mathrm{BO}_2(\mathrm{~g})\) and \(\mathrm{ABO}_3(\mathrm{~s})\) is \(-635, x\) and \(-1210 \mathrm{~kJ} \mathrm{~mol}^{-1}\) respectively. \(\mathrm{ABO}_3(\mathrm{~s}) \rightarrow \mathrm{AO}(\mathrm{s})+\mathrm{BO}_2(\mathrm{~g}) ; \Delta_r \mathrm{H}^{\circ}=175 \mathrm{~kJ} \mathrm{~mol}^{-1}\).
What is the value of \(x\) (in \(\left.\mathrm{kJ} \mathrm{mol}^{-1}\right)\) ?

  1. A -750
  2. B 400
  3. C -400
  4. D 750
Verified Solution

Answer & Solution

Correct Answer

(C) -400

Step-by-step Solution

Detailed explanation

\begin{aligned} & \mathrm{ABO}_3(\mathrm{~s}) \rightarrow \mathrm{AO}(\mathrm{s})+\mathrm{BO}_2(\mathrm{~g}) \Delta_{\mathrm{r}} \mathrm{H}^{\circ}=175 \\ \therefore \quad & \Delta_{\mathrm{r}} \mathrm{H}^{\circ}=\Delta_{\mathrm{f}}…