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TS EAMCET · Chemistry · Electrochemistry

The electrode potential of chlorine electrode is maximum, when the concentration of chloride ion in the solution (in \(\left.\mathrm{mol} \mathrm{L}^{-1}\right)\) is \(\mathrm{X}\). What is the value of \(\mathrm{X}\) ?

  1. A \(2.5 \times 10^{-3}\)
  2. B \(7.5 \times 10^{-3}\)
  3. C \(7.5 \times 10^{-2}\)
  4. D \(2.5 \times 10^{-2}\)
Verified Solution

Answer & Solution

Correct Answer

(A) \(2.5 \times 10^{-3}\)

Step-by-step Solution

Detailed explanation

The nernst equation for reduction potential of an electrode is ;- \(\mathrm{E}=\mathrm{E}^{\circ}-\frac{2.303 \mathrm{RT}}{\mathrm{nF}} \log \frac{\left[\mathrm{Cl}^{-}\right]}{\mathrm{P}_{\mathrm{Cl}_2}}\) or,…
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