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TS EAMCET · Chemistry · Electrochemistry

Identify the correct statements from the folluwing (A) At 298 K, the potential of hydrogen electrode placed in a solution of \(\mathrm{pH}=10\), is -0.59 V (B) The limiting molar conductivity of \(\mathrm{Ca}^{2+}\) and \(\mathrm{Cl}^{-}\)is 119 and \(76 \mathrm{~S} \mathrm{~cm}^2 \mathrm{~mol}^{-1}\) respectively. The limiting molar conductivity of \(\mathrm{CaCl}_2\) is \(195 \mathrm{~S} \mathrm{~cm}^2 \mathrm{~mol}^{-\frac{1}{2}}\) (C) The correct relationship between \(\mathrm{K}_{\mathrm{c}}\) and \(\mathrm{E}_{\text {cell }}^0\) is \(\mathrm{E}_{\mathrm{ccll}}^{-}=\frac{2.303 \mathrm{RT}}{\mathrm{nF}} \log \mathrm{~K}_{\mathrm{c}}\)

  1. A A, B, C
  2. B A, B only
  3. C A, C only
  4. D B, C only
Verified Solution

Answer & Solution

Correct Answer

(C) A, C only

Step-by-step Solution

Detailed explanation

(A) \(\mathrm{E}^{\circ}=-0.059 \mathrm{pH}\) \(\begin{aligned} & =-0.059 \times 10 \\ & =-0.59 \mathrm{~V} \end{aligned}\)…