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TS EAMCET · Chemistry · Electrochemistry

For a half-cell containing a Pt rod immersed in a solution of \(1 \mathrm{M} \mathrm{H} A, \mathrm{O}_2(g)\) is bubbled at \(1 \mathrm{~atm}\). The standard reduction potential for water formation is \(1.23 \mathrm{~V}\). Given a dissociation constant, \(K_a=1 \times 10^{-4}\) for \(\mathrm{H} A\), what is \(E_{\text {Half-cell }}\) at \(298 \mathrm{~K}\) in V ?

  1. A 1.289
  2. B 1.171
  3. C 1.348
  4. D 1.112
Verified Solution

Answer & Solution

Correct Answer

(C) 1.348

Step-by-step Solution

Detailed explanation

Given, Standard reduction potential for water formation \(=1.23 \mathrm{~V}\) Dissociation constant \(\left(K_a\right)\) for \(\mathrm{H} A=1 \times 10^{-4}\) \(E_{\text {half-cell }}\) at \(298 \mathrm{~K}=\) ? Number of electrons \(=2\)…