TS EAMCET · Chemistry · Amines
Arrange the following in the order of decreasing basicity \(\begin{array}{ccc}\mathrm{RN}=\mathrm{CHR}^1 & \mathrm{RC} \equiv \mathrm{N} & \mathrm{RNH}_2 \ \text { I } & \text { II } & \text { III }\end{array}\)
- A I \(>\) III \(>\) II
- B III \(>\) I \(>\) II
- C II \(>\) III \(>\) I
- D II \(>\) I \(>\) III
Answer & Solution
Correct Answer
(B) III \(>\) I \(>\) II
Step-by-step Solution
Detailed explanation
In \(\mathrm{RNH}_2, \mathrm{~N}\) atom is \(\mathrm{sp}^3\) hybridised. In \(\mathrm{RN}=\mathrm{CHR}\), \(\mathrm{N}\) atom is \(\mathrm{sp}^2\) hybridised whereas in \(\mathrm{RC} \equiv \mathrm{N}, \mathrm{N}\) atom is sp hybridised. The sp hybridised \(\mathrm{N}\) atom is…
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