KCET · Chemistry · Chemical Bonding and Molecular Structure
lodoform reaction is answered by all, except
- A \( \mathrm{CH}_{3} \mathrm{CHO} \)
- B (1) \( \mathrm{CH}_{3}-\mathrm{CH}_{2}-\mathrm{CH}_{2} \mathrm{OH} \)
- D \( \mathrm{CH}_{3}-\mathrm{CH}_{2}-\mathrm{OH} \)
Answer & Solution
Correct Answer
(B) (1) \( \mathrm{CH}_{3}-\mathrm{CH}_{2}-\mathrm{CH}_{2} \mathrm{OH} \)
Step-by-step Solution
Detailed explanation
For alcohols secondary and tertiary alcohols gives iodoform reaction and ethanol is the only primary alcohol which gives
iodoform reaction, therefore, propanol will not give iodoform reaction.
(1) \( \underset{\text { Acetaldehyde }}{\mathrm{C}_{3} \mathrm{CH} \mathrm{O}}+3 \mathrm{NaOI} \rightarrow \underset{\text { Yellow ppt }}{\mathrm{CH}}+ \) HCOON \( a+2 \mathrm{NaOH} \)
(2) \( \begin{array}{c}\text { Acetaldehyde } \\ \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{OH}\end{array}+\mathrm{NaOI}_{2}-\mathrm{NaOH}_{\mathrm{S}_{2}}> \) do not give iodoform reaction.
(3) \( \mathrm{CH}_{3}-\stackrel{\mathrm{OH}}{\mathrm{CH}}-\mathrm{CH}_{2} \mathrm{COOH} \) NaOI \( \underset{\text { Yellowppt. }}{\mathrm{CHI}_{3}}+\mathrm{NaOCCH}_{2} \mathrm{COOH} \)
\( \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}-\mathrm{NaOH}_{\mathrm{I}_{2}} \rightarrow \mathrm{CH}_{3} \mathrm{CHO}+\mathrm{NaI}+\mathrm{H}_{2} \mathrm{O} \)
\( \mathrm{CH}_{3} \mathrm{CHO}+3 \mathrm{NaOI} \rightarrow \mathrm{CHI}_{3}+\mathrm{HCOON} a+2 \mathrm{NaOH} \)
iodoform reaction, therefore, propanol will not give iodoform reaction.
(1) \( \underset{\text { Acetaldehyde }}{\mathrm{C}_{3} \mathrm{CH} \mathrm{O}}+3 \mathrm{NaOI} \rightarrow \underset{\text { Yellow ppt }}{\mathrm{CH}}+ \) HCOON \( a+2 \mathrm{NaOH} \)
(2) \( \begin{array}{c}\text { Acetaldehyde } \\ \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{OH}\end{array}+\mathrm{NaOI}_{2}-\mathrm{NaOH}_{\mathrm{S}_{2}}> \) do not give iodoform reaction.
(3) \( \mathrm{CH}_{3}-\stackrel{\mathrm{OH}}{\mathrm{CH}}-\mathrm{CH}_{2} \mathrm{COOH} \) NaOI \( \underset{\text { Yellowppt. }}{\mathrm{CHI}_{3}}+\mathrm{NaOCCH}_{2} \mathrm{COOH} \)
\( \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}-\mathrm{NaOH}_{\mathrm{I}_{2}} \rightarrow \mathrm{CH}_{3} \mathrm{CHO}+\mathrm{NaI}+\mathrm{H}_{2} \mathrm{O} \)
\( \mathrm{CH}_{3} \mathrm{CHO}+3 \mathrm{NaOI} \rightarrow \mathrm{CHI}_{3}+\mathrm{HCOON} a+2 \mathrm{NaOH} \)
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