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KCET · Chemistry · Chemical Bonding and Molecular Structure

lodoform reaction is answered by all, except

  1. A \( \mathrm{CH}_{3} \mathrm{CHO} \)
  2. B (1) \( \mathrm{CH}_{3}-\mathrm{CH}_{2}-\mathrm{CH}_{2} \mathrm{OH} \)
  3. D \( \mathrm{CH}_{3}-\mathrm{CH}_{2}-\mathrm{OH} \)
Verified Solution

Answer & Solution

Correct Answer

(B) (1) \( \mathrm{CH}_{3}-\mathrm{CH}_{2}-\mathrm{CH}_{2} \mathrm{OH} \)

Step-by-step Solution

Detailed explanation

For alcohols secondary and tertiary alcohols gives iodoform reaction and ethanol is the only primary alcohol which gives
iodoform reaction, therefore, propanol will not give iodoform reaction.
(1) \( \underset{\text { Acetaldehyde }}{\mathrm{C}_{3} \mathrm{CH} \mathrm{O}}+3 \mathrm{NaOI} \rightarrow \underset{\text { Yellow ppt }}{\mathrm{CH}}+ \) HCOON \( a+2 \mathrm{NaOH} \)
(2) \( \begin{array}{c}\text { Acetaldehyde } \\ \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{OH}\end{array}+\mathrm{NaOI}_{2}-\mathrm{NaOH}_{\mathrm{S}_{2}}> \) do not give iodoform reaction.
(3) \( \mathrm{CH}_{3}-\stackrel{\mathrm{OH}}{\mathrm{CH}}-\mathrm{CH}_{2} \mathrm{COOH} \) NaOI \( \underset{\text { Yellowppt. }}{\mathrm{CHI}_{3}}+\mathrm{NaOCCH}_{2} \mathrm{COOH} \)
\( \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{OH}-\mathrm{NaOH}_{\mathrm{I}_{2}} \rightarrow \mathrm{CH}_{3} \mathrm{CHO}+\mathrm{NaI}+\mathrm{H}_{2} \mathrm{O} \)
\( \mathrm{CH}_{3} \mathrm{CHO}+3 \mathrm{NaOI} \rightarrow \mathrm{CHI}_{3}+\mathrm{HCOON} a+2 \mathrm{NaOH} \)