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KCET · Chemistry · Aldehydes and Ketones

Benzene carbaldehyde is reacted with concentrated \( \mathrm{NaOH} \) solution to give the products \( \mathrm{A} \) and
B. The product \( A \) can be used food preservative and the product \( B \) is an aromatic hydroxy
compound where \( \mathrm{OH} \) gorup is linked to \( s p^{3} \) hybridised carbon atom next to Benzene ring. The
products \( A \) and \( B \) are respectively,

  1. A Sodium benzoate and phenol
  2. B Sodium benzoate and phenyl methanol
  3. C Sodium benzoate and cresol
  4. D Sodium benzoate and picric acid
Verified Solution

Answer & Solution

Correct Answer

(B) Sodium benzoate and phenyl methanol

Step-by-step Solution

Detailed explanation

This reaction is an example of Cannizzaro reaction.

Benzaldehyde
Sodium benzoate
Benzyl alcohol
(Food preservative)
(Aromatic hydroxy
compound)