KCET · Chemistry · Aldehydes and Ketones
Benzene carbaldehyde is reacted with concentrated \( \mathrm{NaOH} \) solution to give the products \( \mathrm{A} \) and
B. The product \( A \) can be used food preservative and the product \( B \) is an aromatic hydroxy
compound where \( \mathrm{OH} \) gorup is linked to \( s p^{3} \) hybridised carbon atom next to Benzene ring. The
products \( A \) and \( B \) are respectively,
- A Sodium benzoate and phenol
- B Sodium benzoate and phenyl methanol
- C Sodium benzoate and cresol
- D Sodium benzoate and picric acid
Answer & Solution
Correct Answer
(B) Sodium benzoate and phenyl methanol
Step-by-step Solution
Detailed explanation
This reaction is an example of Cannizzaro reaction.

Benzaldehyde
Sodium benzoate
Benzyl alcohol
(Food preservative)
(Aromatic hydroxy
compound)

Benzaldehyde
Sodium benzoate
Benzyl alcohol
(Food preservative)
(Aromatic hydroxy
compound)
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