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KCET · Chemistry · Thermodynamics (C)

A gas can be taken from A to B via two different paths ACB and ADB.

When path ACB is used, \(60\) J of heat flows into the system and \(30\) J of work is done by the system. If path ADB is used, work done by the system is \(10\) J.
The heat flow into the system in path ADB is

  1. A \(80\) J
  2. B \(20\) J
  3. C \(100\) J
  4. D \(40\) J
Verified Solution

Answer & Solution

Correct Answer

(D) \(40\) J

Step-by-step Solution

Detailed explanation

According to the first law of thermodynamics, the change in internal energy is given by:
\(\Delta U = Q - W\)
where \(Q\) is the heat added to the system and \(W\) is the work done by the system.

For path ACB:
Heat added, \(Q_{ACB} = 60\) J
Work done, \(W_{ACB} = 30\) J
\(\Delta U = 60 - 30 = 30\) J

Since internal energy is a state function, the change in internal energy \(\Delta U\) between states A and B is the same for any path. Therefore, for path ADB, \(\Delta U = 30\) J.

For path ADB:
Work done, \(W_{ADB} = 10\) J
Using the first law of thermodynamics again:
\(\Delta U = Q_{ADB} - W_{ADB}\)
\(30 = Q_{ADB} - 10\)
\(Q_{ADB} = 30 + 10 = 40\) J

The heat flow into the system in path ADB is \(40\) J.

Answer: \(40\) J