Consider the following transformations of a compound $\mathrm{P}$.

Choose the correct option(s).

Match each coordination compound in List-I with an appropriate pair of characteristics from List-II and select the correct answer using the code given below the lists
\(\left\{\right.\)en \(= H _2 NCH _2 CH _2 NH _2 ;\) atomic numbers \(\left.: T _{ i }=22, Cr =24 ; Co =27 ; Pt =78\right\}\)

	List – I		List – II
A.	$\left[\mathrm{C}\mathrm{r}{\left(\mathrm{N}{\mathrm{H}}_3\right)}_4\mathrm{C}{\mathrm{l}}_2\right]\mathrm{C}\mathrm{l}$	P.	Paramagnetic and exhibits ionization isomerism
B.	$\left[\mathrm{T}\mathrm{i}{\left({\mathrm{H}}_2\mathrm{O}\right)}_5\mathrm{ }\mathrm{C}\mathrm{l}\right]{\left(\mathrm{N}{\mathrm{O}}_3\right)}_2$	Q.	Diamagnetic and exhibits cis - trans isomerism
C.	$\left[\mathrm{P}\mathrm{t}\left(\mathrm{e}\mathrm{n}\right)\left(\mathrm{N}{\mathrm{H}}_3\right)\mathrm{C}\mathrm{l}\right]\mathrm{N}{\mathrm{O}}_3$	R.	Paramagnetic and exhibits cis - trans isomerism
D.	$\left[\mathrm{C}\mathrm{o}{\left(\mathrm{N}{\mathrm{H}}_3\right)}_4{\left(\mathrm{N}{\mathrm{O}}_3\right)}_2\right]\mathrm{N}{\mathrm{O}}_3$	S.	Diamagnetic and exhibits ionization isomerism

A tin chloride $\mathrm{Q}$ undergoes the following reactions (not balanced)
$\mathrm{Q}+\mathrm{C}{\mathrm{l}}^{-}\to \mathrm{X}$
$\mathrm{Q}+\mathrm{M}{\mathrm{e}}_3\mathrm{N}\to \mathrm{Y}$
$\mathrm{Q}+\mathrm{C}\mathrm{u}\mathrm{C}{\mathrm{l}}_2\to \mathrm{Z}+\mathrm{C}\mathrm{u}\mathrm{C}\mathrm{l}$
$\mathrm{X}$ is a monoanion having pyramidal geometry. Both $\mathrm{Y}$ and $\mathrm{Z}$ are neutral compounds. Choose the correct option(s).

Consider a titration of potassium dichromate solution with acidified Mohr's salt solution using diphenylamine as indicator. The number of moles of Mohr's salt required per mole of dichromate is

Statement I Band gap in germanium is small.
Statement II The energy spread of each germanium atomic energy level is infinitesimally small.

The major product(s) of the following reaction is/are:

If the freezing point of a 0.01 molal aqueous solution of a cobalt (III) chloride-ammonia complex (which behaves as a strong electrolyte) is $-{0.0558}^{\mathrm{o}}\mathrm{C}$ , the number of chloride(s) in the coordination sphere of the complex is
$[{\mathrm{K}}_{\mathrm{f}}\mathrm{ }\mathrm{o}\mathrm{f}\mathrm{ }\mathrm{w}\mathrm{a}\mathrm{t}\mathrm{e}\mathrm{r}=1.86\mathrm{ }\mathrm{K}\mathrm{ }\mathrm{k}\mathrm{g}\mathrm{ }\mathrm{m}\mathrm{o}{\mathrm{l}}^{-1}]$

Two point-like objects of masses $20\mathrm{gm}$ and $30\mathrm{gm}$ are fixed at the two ends of a rigid massless rod of length $10\mathrm{cm}$. This system is suspended vertically from a rigid ceiling using a thin wire attached to its center of mass, as shown in the figure. The resulting torsional pendulum undergoes small oscillations. The torsional constant of the wire is $1.2\times {10}^{-8}\mathrm{N}\mathrm{m}{\mathrm{rad}}^{-1}$. The angular frequency of the oscillations in $n\times {10}^{-3}\mathrm{rad}{\mathrm{s}}^{-1}$. The value of $n$ is _____.

If \(f(x)=\min \left\{1, x^2, x^3\right\}\), then

Let $f: \left(0, \infty \right)\to R$ be a differentiable function such that $f^{\text{'}}\left(x\right)=2-\frac{f\left(x\right)}{x}\forall x\in (0, \infty )$ and $f\left(1\right)\ne 1$. Then,

The surface of copper gets tarnished by the formation of copper oxide. $N_2$ gas was passed to prevent the oxide formation during heating of copper at 1250 K. However, the $N_2$ gas contains 1 mole % of water vapour as impurity. The water vapour oxidises copper as per the reaction given below:

$2Cu\left(s\right)+ H_{2}O\left(g\right)\to C{u}_{2}O\left(s\right) + H_2\left(g\right)$

$P_{H_2}$ Is the minimum partial pressure of $H_2$ (in bar) needed to prevent the oxidation at 1250 K. The value of $\ln \left(p{H}_2\right)$ is ____.

(Given: total pressure \(=1\) bar, R (universal gas constant) \(=8 J K ^{-1} mol^{-1}, \ln (10) =2.3 \cdot Cu (s)\) and \(Cu _2 O (s)\) are mutually immiscible.

At \(1250 K: 2 Cu ( s )+\frac{1}{2} O _2(g) \rightarrow Cu _2 O ( s ) ;\) \(\Delta G^{\ominus}=-78,000 J mol ^{-1}\)

\(H _2(g)+\frac{1}{2} O _2(g) \rightarrow H _2 O ( g ) ; \quad \Delta^{\ominus}=\)\(-1,78,000 J mol ^{-1} ; G\) is the Gibbs energy)/mi> \(\Theta=\) \(-78,000 J mol -1\)

\(H _2(g)+\frac{1}{2} O _2(g) \rightarrow H _2 O ( g ) ; \quad\)\(\Delta^{\ominus}=-1,78,000 J mol ^{-1} ; G\) is the Gibbs energy)

From a point $P\left(\lambda , \lambda , \lambda \right),$ perpendiculars PQ and PR are drawn respectively on the lines $y=x, z=1$ and $y= -x, z= -1$ . If P is such that $\angle QPR$ is a right angle, then the possible value (s) of $\lambda$ is (are)

Let the straight line \(x=b\) divide the area enclosed by \(y=(1-x)^2, y=0\) and \(x=0\) into two parts \(R_1(0 \leq x \leq b)\) and \(R_2(b \leq x \leq 1)\) such that \(R_1-R_2=\frac{1}{4}\). Then, \(b\) equals to