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JEE Advanced · Chemistry · 23. Coordination Compounds

Among the following options, select the option in which each complex in Set-I shows geometrical isomerism and the two complexes in Set-II are ionization isomers of each other.
\(\text { [en } \left.=\mathrm{H}_2 \mathrm{NCH}_2 \mathrm{CH}_2 \mathrm{NH}_2\right]\)

  1. A Set-I: \(\left[\mathrm{Ni}(\mathrm{CO})_4\right]\) and \(\left[\mathrm{PdCl}_2\left(\mathrm{PPh}_3\right)_2\right]\)
    Set-II: \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{Cl}\right] \mathrm{SO}_4\) and \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5\left(\mathrm{SO}_4\right)\right] \mathrm{Cl}\)
  2. B Set-I: \(\left[\mathrm{Co}(\mathrm{en})\left(\mathrm{NH}_3\right)_2 \mathrm{Cl} 2\right]\) and \(\left[\mathrm{PdCl}_2\left(\mathrm{PPh}_3\right)_2\right]\)
    Set-II: \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]\left[\mathrm{Cr}(\mathrm{CN})_6\right]\) and \(\left[\mathrm{Cr}\left(\mathrm{NH}_3\right)_6\right]\left[\mathrm{Co}(\mathrm{CN})_6\right]\)
  3. C Set-I: \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_3\left(\mathrm{NO}_2\right)_3\right]\) and \(\left[\mathrm{Co}(\mathrm{en})_2 \mathrm{Cl}_2\right]\)
    Set-II: \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{Cl}\right] \mathrm{SO}_4\) and \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5\left(\mathrm{SO}_4\right)\right] \mathrm{Cl}\)
  4. D Set-I: \(\left[\mathrm{Cr}\left(\mathrm{NH}_3\right)_5 \mathrm{Cl}\right] \mathrm{Cl}_2\) and \(\left[\mathrm{Co}(\mathrm{en})\left(\mathrm{NH}_3\right)_2 \mathrm{Cl}_2\right]\)
    Set-II: \(\left[\mathrm{Cr}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right] \mathrm{Cl}_3\) and \(\left[\mathrm{Cr}\left(\mathrm{H}_2 \mathrm{O}\right)_5 \mathrm{Cl}\right] \mathrm{Cl}_2 \cdot \mathrm{H}_2 \mathrm{O}\)
Verified Solution

Answer & Solution

Correct Answer

(C) Set-I: \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_3\left(\mathrm{NO}_2\right)_3\right]\) and \(\left[\mathrm{Co}(\mathrm{en})_2 \mathrm{Cl}_2\right]\)
Set-II: \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{Cl}\right] \mathrm{SO}_4\) and \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5\left(\mathrm{SO}_4\right)\right] \mathrm{Cl}\)

Step-by-step Solution

Detailed explanation

Set-I: \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_3\left(\mathrm{NO}_2\right)_3\right]\) and \(\left[\mathrm{Co}(e n)_2 \mathrm{Cl}_2\right]\)
Set-II: \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{Cl}\right] \mathrm{SO}_4\) and \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5\left(\mathrm{SO}_4\right)\right] \mathrm{Cl}\)
Set-I:

Set-II:
\(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{Cl}\right] \mathrm{SO}_4\) and \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5 \mathrm{SO}_4\right] \mathrm{Cl}\) are ionisation isomers.
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