The main product of which of the following reactions gives tertiary sulphonamide with benzene sulphonyl chloride ?

A \(C _6 H _5 Cl +2 NH _3 \xrightarrow[\substack{473 K \\ 60 \text { bar }}]{ Cu _2 O }\)
B \(CH _3 CH _2 NO _2 \xrightarrow{ LiAlH _4}\)
C \(CH _3 CH _2 NC \xrightarrow{ LiAlH _4}\)
D \(CH _3 CONH _2 \xrightarrow[\Delta]{ Br _2 / NaOH }\)

Verified Solution

Answer & Solution

Correct Answer

(C) \(CH _3 CH _2 NC \xrightarrow{ LiAlH _4}\)

Step-by-step Solution

Detailed explanation

\(CH _3 CH _2 NC \xrightarrow[\text { Reduction }]{ LiAlH _4} \underset{2^{\circ} \text {-Amine }}{ CH _3 CH _2 NHCH _3}\)

Apply the relevant identity from the chapter and substitute the values established in the previous step, keeping the original constraint in view.

Use the simplified expression to isolate the unknown, then plug the result back into the question setup to confirm the working is internally consistent.

Cross-check against a boundary or limiting case. Both the dimensional balance and the qualitative behaviour at the extreme should agree with the candidate answer.

Combine the steps above to identify the correct option. The remaining choices each fail at least one of the consistency, dimensional, or boundary checks.

Same subject

Explore more questions on app

From GUJCET

Explore more questions on app

Column - I	Column II
(p) Mendel	(i) Chromosomal theory of Inheritance
(q) Morgan	(ii) Recombination map
(r) Alfred Sturtevant	(iii) Linkage
(s) Sutton	(iv) Law of Segregation