AP EAMCET · Chemistry · General Organic Chemistry
Which one of the following is correct with respect to basic character?
- A \(\mathrm{P}\left(\mathrm{CH}_3\right)_3>\mathrm{PH}_3\)
- B \(\mathrm{PH}_3>\mathrm{P}\left(\mathrm{CH}_3\right)_3\)
- C \(\mathrm{PH}_3>\mathrm{NH}_3\)
- D \(\mathrm{PH}_3=\mathrm{NH}_3\)
Answer & Solution
Correct Answer
(A) \(\mathrm{P}\left(\mathrm{CH}_3\right)_3>\mathrm{PH}_3\)
Step-by-step Solution
Detailed explanation
Due to \(+\mathrm{I}\) effect of 3 methyl groups, the correct basic order is: \(\mathrm{P}\left(\mathrm{CH}_3\right)_3>\mathrm{PH}_3\)
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