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AP EAMCET · Chemistry · p Block Elements (Group 15, 16, 17 & 18)

Which of the following statements are correct?
I. \(\mathrm{P}_4\) molecule is very reactive because of angular strain.
II. The basicity of \(\mathrm{H}_3 \mathrm{PO}_3\) is 3 .
III. In gas phase, all \(\mathrm{P}-\mathrm{Cl}\) bonds of \(\mathrm{PCl}_5\) have same bond length.
IV. In solid state, \(\mathrm{PCl}_5\) exists as an ionic solid, in which anion \(\left[\mathrm{PCl}_6\right]^{-}\)has octahedral and cation \(\left[\mathrm{PCl}_4\right]^{+}\)has tetrahedral shape.

  1. A I and II
  2. B II and IV
  3. C I and IV
  4. D I and III
Verified Solution

Answer & Solution

Correct Answer

(A) I and II

Step-by-step Solution

Detailed explanation

(II) The basicity of \(\mathrm{H}_3 \mathrm{PO}_3\) is 2 , this is because out of the three hydrogen atoms only two are attached to most electronegative oxygen atom and can be removed. (III) \(\mathrm{PCl}_5\) structure is trigonal bipyramidal in which two axial…