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AP EAMCET · Chemistry · s Block Elements

Which of the following statement(s) is/are correct?
(i) \(\mathrm{Li} \mathrm{NO} \mathrm{NO}_3, \mathrm{Ba}\left(\mathrm{NO}_3\right)_2\) both will give \(\mathrm{NO}_2\) on heatiing
(ii) \(\mathrm{BaSO}_4\) is less soluble in water than \(\mathrm{CaSO}_4\)
(iii) Alkaline earth metals do not dissolve in liquid ammonia

  1. A i only
  2. B i, ii only
  3. C i, ii \& iii
  4. D i, iii only
Verified Solution

Answer & Solution

Correct Answer

(B) i, ii only

Step-by-step Solution

Detailed explanation

\(4 \mathrm{Li} \mathrm{NO}_3 \stackrel{\Delta}{\longrightarrow} 2 \mathrm{Li}_2 \mathrm{O}+4 \mathrm{NO}_2+\mathrm{O}_2\) (anomalous behaviour) \(2 \mathrm{Ba}\left(\mathrm{NO}_3\right)_2 \stackrel{\Delta}{\longrightarrow} 2 \mathrm{BaO}+4 \mathrm{NO}_2+\mathrm{O}_2\) Thus, (i)…