ExamBro
ExamBro
AP EAMCET · Chemistry · Chemical Equilibrium

Observe the following solutions
(i) \(1 \mathrm{~L}\) of \(10^{-6} \mathrm{M} \mathrm{Ag} \mathrm{NO}_3\)
(ii) \(1 \mathrm{~L}\) of \(10^{-7} \mathrm{M} \mathrm{AgNO}_3\)
(iii) \(1 \mathrm{~L}\) of \(10^{-9} \mathrm{M} \mathrm{Ag} \mathrm{NO}_3\)
(iv) \(1 \mathrm{~L}\) of \(10^{-3} \mathrm{M} \mathrm{AgNO}_3\)
(v) \(1 \mathrm{~L}\) of \(10^{-5} \mathrm{M} \mathrm{NaCl}\)
Which of the above two solutions when mixed will give a white precipitate, \(\mathrm{AgCl}\) ?
\(\left(\right.\) Given \(\mathrm{K}_{\mathrm{sp}}\) of \(\mathrm{AgCl}=1 \times 10^{-10}\) )

  1. A (i), (v)
  2. B (ii), (v)
  3. C (iv), (v)
  4. D (iii), (v)
Verified Solution

Answer & Solution

Correct Answer

(C) (iv), (v)

Step-by-step Solution

Detailed explanation

A solution that has the concentration of \(\mathrm{Ag}^{+}\)or \(\mathrm{Cl}^{-}\) greater than or equal to the solubility of \(\mathrm{Ag}^{+}\)or \(\mathrm{Cl}^{-}\)from the value of \(K_{s p}\), will precipitate out.…