ExamBro
ExamBro
AP EAMCET · Chemistry · d and f Block Elements

Match the following
\begin{array}{lll}
& \begin{array}{l}
List I \\
(Complex)
\end{array} & \begin{array}{l}
List II \\
(Color)
\end{array} \\
A. \left[\mathrm{Ni}(\mathrm{en})_3\right]^{2+} & I. & Green \\
B. \left[\mathrm{Ni}\left(\mathrm{H}_2 \mathrm{O}\right)_4(\mathrm{en})\right]^{2+} & II. Blue \\
C. \left[\mathrm{Ni}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right]^{2+} & III. Pale blue \\
D. \left[\mathrm{Ni}\left(\mathrm{H}_2 \mathrm{O}\right)_6(\mathrm{en})_2\right]^{2+} & IV. Violet
\end{array}

  1. A A-IV, B-I, C-III, D-II
  2. B A-I, B-II, C-III, D-IV
  3. C A-IV, B-III, C-I, D-II
  4. D A-I, B-III, C-II, D-IV
Verified Solution

Answer & Solution

Correct Answer

(C) A-IV, B-III, C-I, D-II

Step-by-step Solution

Detailed explanation

The splitting energy order is (due to strong-field ligand 'en') :-…