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AP EAMCET · Chemistry · Coordination Compounds

Impure silver ore \(+\mathrm{CN}^{-}+\mathrm{H}_2 \mathrm{O} \xrightarrow{\mathrm{O}_2}[\mathrm{X}]^{-}+\mathrm{OH}^{-}\)
\([\mathrm{X}]^{-}+\mathrm{Zn} \longrightarrow[\mathrm{Y}]^{2-}+\mathrm{Ag}\) (pure)
The co-ordination numbers of the metals in \([\mathrm{X}]\). ( Y\(]\) are respectively

  1. A 3,4
  2. B 1,4
  3. C 4,2
  4. D 2,4
Verified Solution

Answer & Solution

Correct Answer

(D) 2,4

Step-by-step Solution

Detailed explanation

\begin{aligned} & \text { } 4 \mathrm{M}(\mathrm{S})+8 \mathrm{CN}^{-}(\mathrm{aq})+2 \mathrm{H}_2 \mathrm{O}(\mathrm{ag})+\mathrm{O}_2(\mathrm{~g}) \longrightarrow \\ & 4\left[\mathrm{M}(\mathrm{CN})_2\right]^{-}(\mathrm{aq})+4 \overline{\mathrm{O}}…