AP EAMCET · Chemistry · Coordination Compounds
If the crystal field splitting energy of a tetrahedral complex \(\left(\Delta_t\right)\) of the type \(\left[M L_4\right]^{n+}\) is \(x \mathrm{eV}\), what is the crystal field splitting energy with respect to an octahedral complex, \(\left[M L_6\right]^{n+}\) ?
- A \(\frac{9 x}{4} \mathrm{eV}\)
- B \(\frac{9 x}{8} \mathrm{eV}\)
- C \(\frac{4 x}{9} \mathrm{eV}\)
- D \(\frac{4 x}{5} \mathrm{eV}\)
Answer & Solution
Correct Answer
(A) \(\frac{9 x}{4} \mathrm{eV}\)
Step-by-step Solution
Detailed explanation
The crystal field splitting in the tetrahedral field is smaller than in the octahedral field. For most purposes the relationship between tetrahedral and octahedral crystral field splitting may be represented as :…
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