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AP EAMCET · Chemistry · Thermodynamics (C)

If \(\Delta_r \mathrm{H}^{\ominus}\) and \(\Delta_r \mathrm{~S}^{\ominus}\) are standard enthalpy change and standard entropy change respectively for a reaction, the incorrect option is

  1. A \(\Delta_r \mathrm{H}^{\ominus}=\) negative; \(\Delta_r \mathrm{~S}^{\ominus}=\) positive; spontaneous at all temperatures
  2. B \(\Delta_r \mathrm{H}^{\ominus}=\) negative; \(\Delta_r \mathrm{~S}^{\ominus}=\) negative; non-spontaneous at low temperatures
  3. C \(\Delta_r \mathrm{H}^{\ominus}=\) positive; \(\Delta_r \mathrm{~S}^{\ominus}=\) positive; non-spontaneous at low temperatures
  4. D \(\Delta_r \mathrm{H}^{\ominus}=\) negative; \(\Delta_r \mathrm{~S}^{\ominus}=\) negative; spontaneous at low temperatures
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Correct Answer

(B) \(\Delta_r \mathrm{H}^{\ominus}=\) negative; \(\Delta_r \mathrm{~S}^{\ominus}=\) negative; non-spontaneous at low temperatures

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