AP EAMCET · Chemistry · Redox Reactions
Identify the reactions in which dichromate acts as an oxidising reagent.
I. \(\mathrm{Cr}_2 \mathrm{O}_7^{2-}+6 \mathrm{Fe}^{2+}+14 \mathrm{H}^{+} \longrightarrow 2 \mathrm{Cr}^{3+}+6 \mathrm{Fe}^{3+}+7 \mathrm{H}_2 \mathrm{O}\)
II. \(\mathrm{Cr}_2 \mathrm{O}_7^{2-}+2 \mathrm{OH}^{-} \longrightarrow 2 \mathrm{CrO}_4^{2-}+\mathrm{H}_2 \mathrm{O}\)
III. \(\mathrm{Cr}_2 \mathrm{O}_7^{2-}+6 \mathrm{I}^{-}+14 \mathrm{H}^{+} \longrightarrow 2 \mathrm{Cr}^{3+}+3 \mathrm{I}_2+7 \mathrm{H}_2 \mathrm{O}\)
IV. \(\mathrm{Na}_2 \mathrm{Cr}_2 \mathrm{O}_7+2 \mathrm{KCl} \longrightarrow \mathrm{K}_2 \mathrm{Cr}_2 \mathrm{O}_7+2 \mathrm{NaCl}\)
- A I, IV
- B I, III
- C II, III
- D II, IV
Answer & Solution
Correct Answer
(B) I, III
Step-by-step Solution
Detailed explanation
In reaction I and III, dichromate acts as an oxidising reagent. (I) \(\mathrm{Cr}_2 \mathrm{O}_7^{2-}+6 \mathrm{Fe}^{2+}+14 \mathrm{H}^{+} \longrightarrow 2 \mathrm{Cr}^{3+}+6 \mathrm{Fe}^{3+}+7 \mathrm{H}_2 \mathrm{O}\) In the above reaction, \(\mathrm{Cr}^{6+}\) reduced to…
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