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AP EAMCET · Chemistry · Electrochemistry

Find the observed EMF of the cell \(\mathrm{Cd}\left|\mathrm{Cd}^{2+}(0.01 \mathrm{M}) \| \mathrm{Cd}^{2+}(0.01 \mathrm{M})\right| \mathrm{Cd}\) under conditions, internal resistance of \(4 \Omega\) and producing a current of \(0.15 \mathrm{~A}\).
(Given, \(E^{\circ} \mathrm{Cu}^{2+} / \mathrm{Cu}=0.35 \mathrm{~V}\)
and \(\quad E_{\mathrm{Cd}^{2+} / \mathrm{Cd}}^{\circ}=-0.4 \mathrm{~V}\) )

  1. A \(0.75 \mathrm{~V}\)
  2. B \(0.15 \mathrm{~V}\)
  3. C \(0.6 \mathrm{~V}\)
  4. D \(0.9 \mathrm{~V}\)
Verified Solution

Answer & Solution

Correct Answer

(B) \(0.15 \mathrm{~V}\)

Step-by-step Solution

Detailed explanation

The cell representation is \(\mathrm{Cd} / \mathrm{Cd}^{2+}(0.01 \mathrm{M}) \| \mathrm{Cu}^{2+}(0.01 \mathrm{M}) \mid \mathrm{Cu}\) Note In the statement of the question, this portion is written as \({ }^" \mathrm{Cd}^{2+}(0.01 \mathrm{M}) \mid \mathrm{Cd}\) " which is wrong.…
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