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AP EAMCET · Chemistry · Thermodynamics (C)

If for the reaction \(\mathrm{CCl}_4(\mathrm{~g}) \rightarrow \mathrm{C}(\mathrm{g})+4 \mathrm{Cl}(\mathrm{g})\) the following data is given
\(\begin{aligned} & \Delta_{\mathrm{vap}} \mathrm{H}^\theta \mathrm{CCl}_4(\mathrm{l})=30 \mathrm{~kJ} \mathrm{~mol}^{-1} \text {, vap = vaporization } \\ & \Delta_{\mathrm{f}} \mathrm{H}^\theta{ }_{\mathrm{CCl}_4}=-136.0 \mathrm{~kJ} \mathrm{~mol}^{-1}, \mathrm{f}=\text { formation } \\ & \Delta_{\mathrm{a}} \mathrm{H}_{\mathrm{C}}^{\mathrm{q}}=714.0 \mathrm{~kJ} \mathrm{~mol}^{-1}, \mathrm{a}=\text { atomization } \\ & \Delta_{\mathrm{a}} \mathrm{H}^\theta \mathrm{Cl}_2=242.0 \mathrm{~kJ} \mathrm{~mol}^{-1}, \mathrm{a}=\text { atomization }\end{aligned}\)
the bond mean enthalpy of \(\mathrm{C}-\mathrm{Cl}\) in \(\mathrm{CCl}_4(\mathrm{l})\) is

  1. A -319
  2. B 326
  3. C -326
  4. D 292
Verified Solution

Answer & Solution

Correct Answer

(B) 326

Step-by-step Solution

Detailed explanation

\(\mathrm{CCl}_4(\mathrm{~g}) \rightarrow \mathrm{C}(\mathrm{g})+4 \mathrm{Cl}(\mathrm{g})\) or…