सूची \(I\) का सूची \(II\) के साथ मिलान कीजिए:

सूची \(I\) (संकुल) सूची \(II\) (समावयवता का प्रकार)

\(A\). \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5\left(\mathrm{NO}_2\right)\right] \mathrm{Cl}_2\) \(I\).विलायकयोजन समावयवता

\(B\). \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5\left(\mathrm{SO}_4\right)\right] \mathrm{Br}\) \(II\).बंधनी समावयवता

\(C\). \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]\left[\mathrm{Cr}(\mathrm{CN})_6\right]\) \(III\).आयनन समावयवता

\(D\). \(\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right] \mathrm{Cl}_3\) \(IV\). उपसहसंयोजन समावयवता

नीचे दिए गए विकल्पों से सही उत्तर चुनिए:

A \(A-I, B-III, C-IV, D-II\)
B \(A-I, B-IV, C-III, D-II\)
C \(A-II, B-IV, C-III, D-I\)
D \( A-II, B-III, C-IV, D-I\)

Verified Solution

Answer & Solution

Correct Answer

(D) \( A-II, B-III, C-IV, D-I\)

Step-by-step Solution

Detailed explanation

\(A\). \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right) 5\left(\mathrm{NO}_2\right)\right] \mathrm{Cl}_2\)	\(II\). Linkage isomerism due to ' \(N\) ' and ' \(\mathrm{O}\) ' linkage by \(\mathrm{NO}_2\)
\(B\). \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5\left(\mathrm{SO}_4\right)\right] \mathrm{Br}\)	\(III\). Ionization isomerism
\(C\). \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]\left[\mathrm{Cr}(\mathrm{CN})_6\right]\)	\(IV\). Coordination isomerism
\(D\). \(\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right] \mathrm{Cl}_3\)	\(I\). Solvate isomerism

Apply the relevant identity from the chapter and substitute the values established in the previous step, keeping the original constraint in view.

Use the simplified expression to isolate the unknown, then plug the result back into the question setup to confirm the working is internally consistent.

Cross-check against a boundary or limiting case. Both the dimensional balance and the qualitative behaviour at the extreme should agree with the candidate answer.

Combine the steps above to identify the correct option. The remaining choices each fail at least one of the consistency, dimensional, or boundary checks.

Same subject

Explore more questions on app

From NEET

Explore more questions on app

सूची \(I\) (संकुल)	सूची \(II\) (समावयवता का प्रकार)
\(A\). \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5\left(\mathrm{NO}_2\right)\right] \mathrm{Cl}_2\)	\(I\).विलायकयोजन समावयवता
\(B\). \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_5\left(\mathrm{SO}_4\right)\right] \mathrm{Br}\)	\(II\).बंधनी समावयवता
\(C\). \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]\left[\mathrm{Cr}(\mathrm{CN})_6\right]\)	\(III\).आयनन समावयवता
\(D\). \(\left[\mathrm{Co}\left(\mathrm{H}_2 \mathrm{O}\right)_6\right] \mathrm{Cl}_3\)	\(IV\). उपसहसंयोजन समावयवता