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NEET · Chemistry · STD 12 - 2. Electrochemistry

બ્રોમિનની બદલાતી ઓક્સિડેશન અવસ્થાને સુસંગત જુદી જુદી \(emf\) કિંમતો જે નીચે દર્શાવેલ સમજૂતી-ચિત્રમાં (diagram) આપેલ છે તેને ધ્યાનમાં લો. \(\mathrm{BrO}_{4}^{-} \stackrel{1.82 \mathrm{V}}{\longrightarrow} \mathrm{BrO}_{3}^{-} \stackrel{1.5 \mathrm{V}}{\longrightarrow} \mathrm{HBrO}\)\(\stackrel{1.0652 \mathrm{V}}{\longrightarrow} \mathrm{Br}_{2} \stackrel{1.595 \mathrm{V}}{\longrightarrow} \mathrm{Br}^{-}\)  તો વિષમપ્રમાણ (disproportionation) અનુભવતો ઘટક ............

  1. A \(\mathrm{BrO}_{3}^{-} \)
  2. B \(\mathrm{BrO}_{4}^{-} \)
  3. C \(Br_2\)
  4. D \(HBrO\)
Verified Solution

Answer & Solution

Correct Answer

(D) \(HBrO\)

Step-by-step Solution

Detailed explanation

Calculate \(E_{cell}^o\) corresponding to each compound under golng disproportlonation reactlon. The reaction for which \(\mathrm{E}_{\text {cell }}^{\circ}\) comes out \(+ve\) is spontaneous. \(\mathrm{HBrO} \longrightarrow \mathrm{Br}_{2} \quad \mathrm{E}^{\circ}=1.595,\) SRP (cathode)
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