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WBJEE · Chemistry · Electrochemistry

The equivalent conductance of \(\mathrm{NaCl}, \mathrm{HCl}\) and \(\mathrm{CH}_3 \mathrm{COONa}\) at infinite dilution are \(126.45,426.16\) and 91 \(\mathrm{ohm}^{-1} \mathrm{~cm}^2 \mathrm{eq}^{-1}\) respectively at \(25^{\circ} \mathrm{C}\). The equivalent conductance of acetic acid (at infinite dilution) would be

  1. A \(461.61 \mathrm{~ohm}^{-1} \mathrm{~cm}^2 \mathrm{~eq}^{-1}\)
  2. B \(390.71 \mathrm{~ohm}^{-1} \mathrm{~cm}^2 \mathrm{~eq}^{-1}\)
  3. C cannot be determined from the given data
  4. D \(208.71 \mathrm{~ohm}^{-1} \mathrm{~cm}^2 \mathrm{~eq}^{-1}\)
Verified Solution

Answer & Solution

Correct Answer

(B) \(390.71 \mathrm{~ohm}^{-1} \mathrm{~cm}^2 \mathrm{~eq}^{-1}\)

Step-by-step Solution

Detailed explanation

Hint : According to Kohlrausch's law…