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TS EAMCET · Chemistry · p Block Elements (Group 13 & 14)

What is the nature of the bonding in anhydrous \(\mathrm{AlCl}_3\) and hydrated \(\mathrm{AlCl}_3\) respectively?

  1. A Ionic and ionic
  2. B Ionic and covalent
  3. C Covalent and ionic
  4. D Covalent and covalent
Verified Solution

Answer & Solution

Correct Answer

(C) Covalent and ionic

Step-by-step Solution

Detailed explanation

Many simple compounds of elements such as \(\mathrm{AlCl}_3, \mathrm{GaCl}_3\) and \(\mathrm{InCl}_3\) are covalent while anhydrous but in aqueous solution, these are ionic in nature. In anhydrous condition, the (charge/radius) ratio, i.e. polarisability of \(\mathrm{Al}^{3+}\)…