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TS EAMCET · Chemistry · Thermodynamics (C)

For the reaction at \(25^{\circ} \mathrm{C}, \mathrm{X}_2 \mathrm{O}_4(\mathrm{l}) \longrightarrow 2 \mathrm{XO}_2(\mathrm{~g}), \Delta \mathrm{U}\) and \(\Delta \mathrm{S}\) are \(2.1 \mathrm{~K}\). Cal and \(20 \mathrm{Cal} / \mathrm{K}\) respectively. What is \(\Delta \mathrm{G}\) for the reaction at the same temperature? \((\mathrm{R}=2 \mathrm{Cal}\) \(\left.\mathrm{K}^{-1} \mathrm{~mol}^{-1}\right)\)

  1. A -2.67 k. Cal
  2. B \(+2.67 \mathrm{k} . \mathrm{Cal}\)
  3. C \(-1.67 \mathrm{k} . \mathrm{Cal}\)
  4. D \(+3.67 \mathrm{k} . \mathrm{Cal}\)
Verified Solution

Answer & Solution

Correct Answer

(A) -2.67 k. Cal

Step-by-step Solution

Detailed explanation

\(\Delta \mathrm{G}=\Delta \mathrm{H}-\mathrm{T} \Delta \mathrm{S}\) and \(\Delta \mathrm{H}=\Delta \mathrm{U}+\mathrm{P} \Delta \mathrm{V}\)…