TS EAMCET · Chemistry · Electrochemistry

Assertion (A) : A current of \(96.5 \mathrm{~A}\) is passed into aqueous \(\mathrm{AgNO}_3\) solution for \(100 \mathrm{~s}\). The weight of silver deposited is \(10.8 \mathrm{~g}\) (At. wt. of \(\mathrm{Ag}=108)\)Reason (R) : The mass of a substance deposited during the electrolysis of an electrolyte is inversely proportional to the quantity of electricity passing through the electrolyte. The correct answer is :

A Both (A) and (R) are true and (R) is the correct explanation of (A)
B Both (A) and (R) are true but (R) is not the correct explanation of (A)
C (A) is true but (R) is false
D (A) is false but (R) is true

Verified Solution

Answer & Solution

Correct Answer

(C) (A) is true but (R) is false

Step-by-step Solution

Detailed explanation

\(i=96.5 \mathrm{~A}, t=100 \mathrm{~s}\) \(w=108\) \(Q=i t\) \(Q=96.5 \times 100=9650 \mathrm{C}\) \(\because 96500\) coulomb deposited wt. of \(\mathrm{Ag}=108 \mathrm{~g}\) \(\therefore 9650\) coulomb deposited wt. of Ag \(=\frac{108 \times 9650}{96500}\) So, statement…

Apply the relevant identity from the chapter and substitute the values established in the previous step, keeping the original constraint in view.

Use the simplified expression to isolate the unknown, then plug the result back into the question setup to confirm the working is internally consistent.

Cross-check against a boundary or limiting case. Both the dimensional balance and the qualitative behaviour at the extreme should agree with the candidate answer.

Combine the steps above to identify the correct option. The remaining choices each fail at least one of the consistency, dimensional, or boundary checks.

Same subject

Explore more questions on app

From TS EAMCET

Explore more questions on app