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TS EAMCET · Chemistry · General Organic Chemistry

Arrange the following phenols in decreasing order of their \(\mathrm{pK}_{\mathrm{a}}\)

  1. A D > B > C > A
  2. B A > C > B > D
  3. C A > C > D > B
  4. D B > D > C > A
Verified Solution

Answer & Solution

Correct Answer

(B) A > C > B > D

Step-by-step Solution

Detailed explanation

Acidity \(\propto \frac{1}{\mathrm{P}_{\mathrm{ka}}} \propto-\) Ieffect The correct order of \(\mathrm{P}_{\mathrm{ka}}\) is Phenol \(>\) meta-nitrophenol \(>\) ortho-nitrophenol > para-nitrophenol.
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