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NEET · Chemistry · STD 12 - 5. Co-ordination chemistry

Which of the following species is not stable ?

  1. A \(\left[\mathrm{SiF}_{6}\right]^{2-}\)
  2. B \(\left[\mathrm{GeCl}_{6}\right]^{2-}\)
  3. C \(\left[\mathrm{Sn}(\mathrm{OH})_{6}\right]^{2-}\)
  4. D \(\left[\mathrm{SiCl}_{6}\right]^{2-}\)
Verified Solution

Answer & Solution

Correct Answer

(D) \(\left[\mathrm{SiCl}_{6}\right]^{2-}\)

Step-by-step Solution

Detailed explanation

\(\mathrm{SiCl}_{6}^{2-}\) does not exist since (i) size of \(\mathrm{Cl}^{-}\) is large so it cannot accommodate around \(\mathrm{Si}^{+4}\) due to limitation of slze
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