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NEET · Chemistry · STD 12 - 7. Alcohol, phenol and ethers
The major products \(\mathrm{C}\) and \(\mathrm{D}\) formed in the following reactions respectively are \(\mathrm{C}\mathrm{H}_{3} -\mathrm{CH}_{2}-\mathrm{CH}_{2}-\mathrm{O}-\mathrm{C}\left(\mathrm{CH}_{3}\right)_{3} \xrightarrow[\Delta]{{\mathrm{excess} \mathrm{HI}}} \mathrm{C}+\mathrm{D}\)
- A \( \mathrm{H}_{3} \mathrm{C}-\mathrm{CH}_{2}-\mathrm{CH}_{2}-\mathrm{CH}_{2}-\mathrm{I}\) and \(\mathrm{I}-\mathrm{C}\left(\mathrm{CH}_{3}\right)_{3}\)
- B \(\mathrm{H}_{3} \mathrm{C}-\mathrm{CH}_{2}-\mathrm{CH}_{2}-\mathrm{OH}\) and \(\mathrm{I}-\mathrm{C}\left(\mathrm{CH}_{3}\right)_{3}\)
- C \(\mathrm{H}_{3} \mathrm{C}-\mathrm{CH}_{2}-\mathrm{CH}_{2}-\mathrm{I}\) and \(\mathrm{HO}-\mathrm{C}\left(\mathrm{CH}_{3}\right)_{3}\)
- D \(\mathrm{H}_{3} \mathrm{C}-\mathrm{CH}_{2}-\mathrm{CH}_{2}-\mathrm{OH}\) and \(\mathrm{HO}-\mathrm{C}\left(\mathrm{CH}_{3}\right)_{3}\)
Answer & Solution
Correct Answer
(A) \( \mathrm{H}_{3} \mathrm{C}-\mathrm{CH}_{2}-\mathrm{CH}_{2}-\mathrm{CH}_{2}-\mathrm{I}\) and \(\mathrm{I}-\mathrm{C}\left(\mathrm{CH}_{3}\right)_{3}\)
Step-by-step Solution
Detailed explanation
\(\mathrm{C}\mathrm{H}_{3} -\mathrm{CH}_{2}-\mathrm{CH}_{2}-\mathrm{O}-\mathrm{C}\left(\mathrm{CH}_{3}\right)_{3} \xrightarrow[\Delta]{{\mathrm{excess} \mathrm{HI}}} \) \(\mathrm{CH}_{3}-\mathrm{CH}_{2}-\mathrm{CH}_{2}-\mathrm{OH}+\left(\mathrm{CH}_{3}\right)_{3} \mathrm{C}-I\xrightarrow[\Delta]{{\mathrm{\;} \mathrm{HI}}}\)\(\mathrm{CH}_{3}-\mathrm{CH}_{2}-\mathrm{CH}_{2}-\mathrm{I}\)
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