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NEET · Chemistry · STD 12 - 4. d and f- block elements

Reason of lanthanoid contraction is

  1. A negligible screening effect of \('f'-\)orbitals
  2. B increasing nuclear charge
  3. C decreasing nuclear charge
  4. D decreasing screening effect.
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Answer & Solution

Correct Answer

(A) negligible screening effect of \('f'-\)orbitals

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Detailed explanation

Lanthanoid contraction is the regular decrease in atomic and ionic radii of lanthanides. This is due to the imperfect shielding [or poor screening effect ] of \(l-\)orbitals due to their diffused shape which unable to counterbalance the effect to the increased nuclear charge. Hence, the net result is a contraction in size of lanthanoids.