NEET · Chemistry · STD 11 - 9. Hydricarbon
Predict the correct intermediate and product in the following reaction : \({H_3}C - C \equiv CH\,\xrightarrow[{HgS{O_4}}]{{{H_2}O,\,{H_2}S{O_4}}}\,\mathop {Intermediate}\limits_{(A)} \,\)\( \to \,\mathop {\Pr oduct}\limits_{(B)} \)
- A \(A \,: \, \begin{array}{*{20}{c}}
{{H_3}C - C = C{H_2}} \\
| \\
{OH}
\end{array}\) \( B\,\, :\, \begin{array}{*{20}{c}}
{{H_3}C - C = C{H_2}} \\
| \\
{S{O_4}}
\end{array}\) - B \(A\,\, :\,\begin{array}{*{20}{c}}
{{H_3}C - C - C{H_3}} \\
{|\,|} \\
O
\end{array}\) \(B\,\,:\, H_3C-C=CH\) - C \(A \,: \, \begin{array}{*{20}{c}}
{{H_3}C - C = C{H_2}} \\
| \\
{OH}
\end{array}\) \(B\,\, :\,\begin{array}{*{20}{c}}
{{H_3}C - C - C{H_3}} \\
{|\,|} \\
O
\end{array}\) - D \( A\,\, :\, \begin{array}{*{20}{c}}
{{H_3}C - C = C{H_2}} \\
| \\
{S{O_4}}
\end{array}\) \(B\,\, :\,\begin{array}{*{20}{c}}
{{H_3}C - C - C{H_3}} \\
{|\,|} \\
O
\end{array}\)
Answer & Solution
Correct Answer
(C) \(A \,: \, \begin{array}{*{20}{c}}
{{H_3}C - C = C{H_2}} \\
| \\
{OH}
\end{array}\) \(B\,\, :\,\begin{array}{*{20}{c}}
{{H_3}C - C - C{H_3}} \\
{|\,|} \\
O
\end{array}\)
Step-by-step Solution
Detailed explanation
\(C{{H}_{3}}-C\equiv CH\xrightarrow[HgS{{O}_{4}}]{{{H}_{2}}O.{{H}_{2}}S{{O}_{4}}}\begin{matrix}
C{{H}_{3}}-C=C{{H}_{2}} \\
|\,\, \\
\,\,\,OH \\
\end{matrix}\) \(\xrightarrow{Tautomerism}\begin{matrix}
CH3-C-C{{H}_{3}} \\
|| \\
O \\
\end{matrix}\)
C{{H}_{3}}-C=C{{H}_{2}} \\
|\,\, \\
\,\,\,OH \\
\end{matrix}\) \(\xrightarrow{Tautomerism}\begin{matrix}
CH3-C-C{{H}_{3}} \\
|| \\
O \\
\end{matrix}\)
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