NEET · Chemistry · STD 12 - 5. Co-ordination chemistry
Match List I with List II :
| List-I (Complex) | List-II (Type of isomerism) |
| (A) \(\left[ Pt \left( NH _3\right)_2 Cl _2\right]\) | (I) Optical |
| (B) \(\left[ Co ( en )_3\right]^{3+}\) | (II) Solvate |
| (C) \(\left[ Co \left( NH _3\right)_5 NO _2\right] Cl _2\) | (III) Geometrical |
| (D) \(\left[ Cr \left( H _2 O \right)_6\right] Cl _3\) | (IV) Linkage |
- A A-III, B-I, C-II, D-IV
- B A-I, B-III, C-II, D-IV
- C A-II, B-IV, C-III, D-I
- D A-III, B-I, C-IV, D-II
Answer & Solution
Correct Answer
(D) A-III, B-I, C-IV, D-II
Step-by-step Solution
Detailed explanation
(D) A-III, B-I, C-IV, D-II
A. \(\left[ Pt \left( NH _3\right)_2 Cl _2\right]\) is a square planar complex of the type \(M A_2 B_2\). It exhibits geometrical isomerism (cis and trans forms).
B. \(\left[ Co ( en )_3\right]^{3+}\) is an octahedral complex with three symmetrical bidentate ligands. It lacks a plane of symmetry and exhibits optical isomerism.
C. \(\left[ Co \left( NH _3\right)_5 NO _2\right] Cl _2\) contains the ambidentate ligand \(NO _2^{-}\), which can coordinate through either the nitrogen or oxygen atom. It exhibits linkage isomerism.
D. \(\left[ Cr \left( H _2 O \right)_6\right] Cl _3\) can exchange water molecules with chloride ions to form different hydrate isomers. It exhibits solvate isomerism.
Therefore, the correct matching is A-III, B-I, C-IV, D-II.
A. \(\left[ Pt \left( NH _3\right)_2 Cl _2\right]\) is a square planar complex of the type \(M A_2 B_2\). It exhibits geometrical isomerism (cis and trans forms).
B. \(\left[ Co ( en )_3\right]^{3+}\) is an octahedral complex with three symmetrical bidentate ligands. It lacks a plane of symmetry and exhibits optical isomerism.
C. \(\left[ Co \left( NH _3\right)_5 NO _2\right] Cl _2\) contains the ambidentate ligand \(NO _2^{-}\), which can coordinate through either the nitrogen or oxygen atom. It exhibits linkage isomerism.
D. \(\left[ Cr \left( H _2 O \right)_6\right] Cl _3\) can exchange water molecules with chloride ions to form different hydrate isomers. It exhibits solvate isomerism.
Therefore, the correct matching is A-III, B-I, C-IV, D-II.
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