NEET · Chemistry · STD 12 - 5. Co-ordination chemistry
Given below are two statements : Statement I: Both \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right) 6\right]^{3+}\) and \(\left[\mathrm{CoF}_6\right]^3\) complexes are octahedral but differ in their magnetic behaviour. Statement II: \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)\right]^{3+}\) is diamagnetic whereas \(\left[\mathrm{CoF} \mathrm{F}_6\right]^{3-}\) is paramagnetic. In the light of the above statements, choose the correct answer from the options given below:
- A Both Statement \(I\) and Statement \(II\) are false
- B Statement \(I\) is true but Statement \(II\) is false
- C Statement \(I\) is false but Statement \(II\) is true
- D Both Statement \(I\) and Statement \(II\) are true
Answer & Solution
Correct Answer
(D) Both Statement \(I\) and Statement \(II\) are true
Step-by-step Solution
Detailed explanation
In \(\left[\mathrm{Co}\left(\mathrm{NH}_3\right)_6\right]^{3+}, \mathrm{Co}^{3+}\) ion is having \(3 \mathrm{~d}^6\) configuration. Electronic configuration of \(\mathrm{Co}^{3+}\) \(Image\)
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