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NEET · Chemistry · STD 12 - 2. Electrochemistry

For the cell reaction......\(kJ\, mol^{-1}\) \(2 \mathrm{Fe}^{3+}(\mathrm{aq})+2 \mathrm{I^-}(\mathrm{aq}) \rightarrow 2 \mathrm{Fe}^{2+}(\mathrm{aq})+\mathrm{I}_{2}(\mathrm{aq})\) \(\mathrm{E}_{\text {call }}^{\mathrm{e}}=0.24 \mathrm{V}\) at \(298\; \mathrm{K}\). The standard Gibbs energy \(\left( {{\Delta _r}{{\rm{G}}^ \ominus }} \right)\) of the cell reaction is: [Faraday constant \(\mathrm{F}=96500 \;\mathrm{C} \mathrm{mol}^{-1} \)]

  1. A \(-46.32\)
  2. B \(-23.16 \)
  3. C \(46.32 \)
  4. D \(23.16\)
Verified Solution

Answer & Solution

Correct Answer

(A) \(-46.32\)

Step-by-step Solution

Detailed explanation

\(2 \mathrm{Fe}^{3+}(\mathrm{aq})+2 \mathrm{I}(\mathrm{aq}) \rightarrow 2 \mathrm{Fe}^{2+}(\mathrm{aq})+\mathrm{I}_{2}(\mathrm{aq})\) \(\mathrm{n}=2\)