Consider the reaction, \(CH_3CH_2CH_2Br + NaCN \to \)\(CH_3CH_2CH_2CN+ NaBr\) This reaction will be the fastest in

A ethanol
B methanol
C \(N, N'-\) dimethylformamide \((DMF)\)
D water

Verified Solution

Answer & Solution

Correct Answer

(C) \(N, N'-\) dimethylformamide \((DMF)\)

Step-by-step Solution

Detailed explanation

\(\mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{Br}+\mathrm{NaCN} \rightarrow \mathrm{CH}_{3} \mathrm{CH}_{2} \mathrm{CH}_{2} \mathrm{CN}+\mathrm{NaBr}\) follows \({{S}_{{{N}^{2}}}}\) mechanism which is favoured by polar aprotic solvent l.e.. \(N, N'\) - dimethylformamide \((DMF)\)

Apply the relevant identity from the chapter and substitute the values established in the previous step, keeping the original constraint in view.

Use the simplified expression to isolate the unknown, then plug the result back into the question setup to confirm the working is internally consistent.

Cross-check against a boundary or limiting case. Both the dimensional balance and the qualitative behaviour at the extreme should agree with the candidate answer.

Combine the steps above to identify the correct option. The remaining choices each fail at least one of the consistency, dimensional, or boundary checks.

Same subject

Explore more questions on app

From NEET

Match List I with List II:

\(\text{List - I (Ion)}\)	\(\text{List - II (Group Number}\) \(\text{in Cation Analysis)}\)
A. \(\text{Co} ^{2+}\)	(I) \(\text{Group - I}\)
B. \(\text{Mg} ^{2+}\)	(II) \(\text{Group - III}\)
C. \(\text{Pb} ^{2+}\)	(III) \(\text{Group - IV}\)
D. \(\text{Al} ^{3+}\)	(IV) \(\text{Group - VI}\)

NEET 2025 Medium

Explore more questions on app