Consider the nitration of benzene using mixed conc. \(H_2SO_4\) and \(HNO_3. \) If a large amount of \(KHSO_4\) is added to the mixture, the rate of nitration will be

A unchanged
B doubled
C faster
D slower.

Verified Solution

Answer & Solution

Correct Answer

(D) slower.

Step-by-step Solution

Detailed explanation

\(\mathrm{H}_{2} \mathrm{SO}_{4}+\stackrel{\oplus}{\mathrm{H}} \longrightarrow \mathrm{NO}_{2}+\mathrm{H \stackrel{\ominus}{S}O}_{4}+\mathrm{H}_{2} \mathrm{O}\) \(\mathrm{KHSO}_{4} \longrightarrow \mathrm{K}^{\oplus}+\mathrm{H\stackrel{\ominus}{S}O}_{4}\)

Apply the relevant identity from the chapter and substitute the values established in the previous step, keeping the original constraint in view.

Use the simplified expression to isolate the unknown, then plug the result back into the question setup to confirm the working is internally consistent.

Cross-check against a boundary or limiting case. Both the dimensional balance and the qualitative behaviour at the extreme should agree with the candidate answer.

Combine the steps above to identify the correct option. The remaining choices each fail at least one of the consistency, dimensional, or boundary checks.

Same subject

The values of \(K_{sp}\) of \(CaCO_3\) and \(CaC_2O_4\) are \(4.7 \times 10^{-9}\) and \(1.3 \times 10^{-9}\) respectively at \(25\,^oC.\) If the mixture of these two is washed with water, what is the concentration of \(Ca^{2+}\) ions in water ..............\( \times 10^{-5}\, M\)?

NEET 2013 Hard

Match List-\(I\) with List-\(II\).

List-\(I\) (Molecule)	List-\(II\). (Number and types of bond/s between two carbon atoms)
\(A\). ethane	\(I\). one \(\sigma\)-bond and two \(\pi\)-bonds
\(B\). ethene	\(II\). two \(\pi\)-bonds
\(C\). carbon molecule, \(\mathrm{C}_2\)	\(III\). one \(\sigma\)-bond
\(D\). ethyne	\(IV\). one \(\sigma\)-bond and one \(\pi\)-bond

Choose the correct answer from the options given below:

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