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NEET · Chemistry · STD 12 -8.1. Aldehydes and ketones

Carboxylic acid have higher boiling points than aldehydes, ketones and even alcohols of comparable molecular mass. It is due to their

  1. A formation of intramolecular \(H-\)bonding
  2. B formation of carboxylate ion
  3. C more extensive association of carboxylic acid via van der Waals force of attraction
  4. D formation of intermolecular \(H-\)bonding.
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Answer & Solution

Correct Answer

(D) formation of intermolecular \(H-\)bonding.

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Detailed explanation

Carboxylic acid has higher boiling point than aldehyde, ketone and even alcohols of comparable molecular mass. This is due to more extensive association through intermolecular \(H-\)bonding.
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