MHT CET · Physics · Atomic Physics
In Lyman series, series limit of wavelength is \(\lambda_1\). The wavelength of first line of Lyman series is \(\lambda_2\) and in Balmer series, the series limit of wavelength is \(\lambda_3\). Then the relation between \(\lambda_1\), \(\lambda_2\) and \(\lambda_3\) is
- A \(\lambda_1=\lambda_2+\lambda_3\)
- B \(\lambda_2=\lambda_1+\lambda_3\)
- C \(\frac{1}{\lambda_1}=\frac{1}{\lambda_2}-\frac{1}{\lambda_3}\)
- D \(\frac{1}{\lambda_1}-\frac{1}{\lambda_2}=\frac{1}{\lambda_3}\)
Answer & Solution
Correct Answer
(D) \(\frac{1}{\lambda_1}-\frac{1}{\lambda_2}=\frac{1}{\lambda_3}\)
Step-by-step Solution
Detailed explanation
According to Rydberg's formula,
\(
\frac{1}{\lambda}=R\left(\frac{1}{\mathrm{n}^2}-\frac{1}{\mathrm{~m}^2}\right)
\)
For series limit of Lyman series, \(\mathrm{n}=1, \mathrm{~m}=\infty, \lambda=\lambda_1\)
\(
\therefore \frac{1}{\lambda_1}=\mathrm{R}
\)
For \(1^{\text {st }}\) line of Lyman series,
\(
\mathrm{n}=1, \mathrm{~m}=2, \lambda=\lambda_2
\)
\(
\therefore \frac{1}{\lambda_2}=\frac{3 R}{4}
\)
For series limit of Balmer series,
\(\mathrm{n}=2, \mathrm{~m}=\infty, \lambda=\lambda_3 \)
\( \therefore \frac{1}{\lambda_3}=\frac{\mathbb{R}}{4} \)
\( \text {Now, } \frac{1}{\lambda_1}-\frac{1}{\lambda_2}=\mathbb{R}-\frac{3 \mathrm{R}}{4}=\frac{\mathbb{R}}{4} \)
\( \therefore \frac{1}{\lambda_1}-\frac{1}{\lambda_2}=\frac{1}{\lambda_3}\)
\(
\frac{1}{\lambda}=R\left(\frac{1}{\mathrm{n}^2}-\frac{1}{\mathrm{~m}^2}\right)
\)
For series limit of Lyman series, \(\mathrm{n}=1, \mathrm{~m}=\infty, \lambda=\lambda_1\)
\(
\therefore \frac{1}{\lambda_1}=\mathrm{R}
\)
For \(1^{\text {st }}\) line of Lyman series,
\(
\mathrm{n}=1, \mathrm{~m}=2, \lambda=\lambda_2
\)
\(
\therefore \frac{1}{\lambda_2}=\frac{3 R}{4}
\)
For series limit of Balmer series,
\(\mathrm{n}=2, \mathrm{~m}=\infty, \lambda=\lambda_3 \)
\( \therefore \frac{1}{\lambda_3}=\frac{\mathbb{R}}{4} \)
\( \text {Now, } \frac{1}{\lambda_1}-\frac{1}{\lambda_2}=\mathbb{R}-\frac{3 \mathrm{R}}{4}=\frac{\mathbb{R}}{4} \)
\( \therefore \frac{1}{\lambda_1}-\frac{1}{\lambda_2}=\frac{1}{\lambda_3}\)
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