MHT CET · Physics · Atomic Physics

' \(\lambda_1\) ' is the wavelength of series limit of Lyman series, ' \(\lambda_2\) ' is the wavelength of the first line of Lyman series and ' \(\lambda_3\) ' is the series limit of the Balmer series. Then the relation between ' \(\lambda_1\) ' \(\lambda_2\) and \(\lambda_3\) is

A \(\frac{1}{\lambda_1}-\frac{1}{\lambda_2}=\frac{1}{\lambda_3}\)
B \(\frac{1}{\lambda_1}=\frac{1}{\lambda_2}-\frac{1}{\lambda_3}\)
C \(\lambda_2=\lambda_1+\lambda_3\)
D \(\lambda_1=\lambda_2+\lambda_3\)

Verified Solution

Answer & Solution

Correct Answer

(A) \(\frac{1}{\lambda_1}-\frac{1}{\lambda_2}=\frac{1}{\lambda_3}\)

Step-by-step Solution

Detailed explanation

Series limit of Lyman series is given by
\(
\frac{1}{\lambda_1}=\mathrm{R}\left(\frac{1}{1}-\frac{1}{\infty}\right)=\mathrm{R}
\)
Series limit of Balmer series given by
\(
\frac{1}{\lambda_3}=\mathrm{R}\left(\frac{1}{4}-\frac{1}{\infty}\right)=\frac{\mathrm{R}}{4}
\)
First line of Lyman series is given by
\(
\begin{aligned}
& \frac{1}{\lambda_2}=\mathrm{R}\left(\frac{1}{1}-\frac{1}{4}\right)=\mathrm{R}-\frac{\mathrm{R}}{4}=\frac{1}{\lambda_1}-\frac{1}{\lambda_3} \\
& \therefore \frac{1}{\lambda_1}-\frac{1}{\lambda_2}=\frac{1}{\lambda_3}
\end{aligned}
\)

Apply the relevant identity from the chapter and substitute the values established in the previous step, keeping the original constraint in view.

Use the simplified expression to isolate the unknown, then plug the result back into the question setup to confirm the working is internally consistent.

Cross-check against a boundary or limiting case. Both the dimensional balance and the qualitative behaviour at the extreme should agree with the candidate answer.

Combine the steps above to identify the correct option. The remaining choices each fail at least one of the consistency, dimensional, or boundary checks.

Same subject

Explore more questions on app

From MHT CET

Explore more questions on app