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MHT CET · Chemistry · General Organic Chemistry

Which of the following group is sharp ortho and para directive?

  1. A \(-\mathrm{C}_{6} \mathrm{H}_{5}\)
  2. B \(-\mathrm{OH}\)
  3. C \(\mathrm{CH}_{3}\)
  4. D \(-\mathrm{Cl}\)
Verified Solution

Answer & Solution

Correct Answer

(B) \(-\mathrm{OH}\)

Step-by-step Solution

Detailed explanation

All the groups are \(o\) - and \(p\) -directive. But in
-OH group, lone pair of electron present at \(o\) -atom, increases electron density for electrophile at \(o^{-}\) and \(p\) -positions. Thus, it is sharp \(o\) - and \(p\) - directive.