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MHT CET · Chemistry · Electrochemistry

Which from following statements is true regarding the cell emf at 298 K for \(\stackrel{\ominus}{\mathrm{Ni}}{ }_{(\mathrm{s})}|\stackrel{+2}{\mathrm{Ni}}(0 \cdot 01 \mathrm{M})|\left|\mathrm{Ag}^{+}(0 \cdot 01 \mathrm{M})\right| \mathrm{Ag}_{(\mathrm{s})}^{\oplus}\)

  1. A less than \(E^{\circ}{ }_{\text {cell }}\) by 0.0592 V
  2. B greater than \(\mathrm{E}^{\circ}{ }_{\text {cell }}\) by 0.0592 V
  3. C less than \(E^{\circ}{ }_{\text {cell }}\) by 0.0296 V
  4. D greater than \(\mathrm{E}^{\circ}{ }_{\text {cell }}\) by 0.0296 V
Verified Solution

Answer & Solution

Correct Answer

(A) less than \(E^{\circ}{ }_{\text {cell }}\) by 0.0592 V

Step-by-step Solution

Detailed explanation

\( \mathrm{Ni}_{(\mathrm{s})} + 2\mathrm{Ag}^{+}_{(\mathrm{aq})} \rightarrow \mathrm{Ni}^{2+}_{(\mathrm{aq})} + 2\mathrm{Ag}_{(\mathrm{s})} \) \( n = 2 \)