MHT CET · Chemistry · Coordination Compounds
Which following pair of structure and magnetic properties is correct for tetracyanonickalate (II) ion?
- A Square planar, paramagnetic
- B Tetrahedral, diamagnetic
- C Square planar, diamagnetic
- D Tetrahedral, paramagnetic
Answer & Solution
Correct Answer
(C) Square planar, diamagnetic
Step-by-step Solution
Detailed explanation
\(\left[\mathrm{Ni}(\mathrm{CN})_4\right]^{-2}\)

In the presence of \(\mathrm{CN}^{-}\)strong field ligand

Square planar geometry diamagnetic in nature

In the presence of \(\mathrm{CN}^{-}\)strong field ligand

Square planar geometry diamagnetic in nature
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