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MHT CET · Chemistry · General Organic Chemistry

Which among the following substituent groups decreases the acidic strength of aromatic carboxylic acid?

  1. A \(-\mathrm{NH}_{2}\)
  2. B \(-\mathrm{CN}\)
  3. C \(-\mathrm{Cl}\)
  4. D \(-\mathrm{N} \mathrm{O}_{2}\)
Verified Solution

Answer & Solution

Correct Answer

(A) \(-\mathrm{NH}_{2}\)

Step-by-step Solution

Detailed explanation

\(-\mathrm{NH}_{2}\) is electron donating group which activate the benzene ring to electrophilic attack and make aromatic carboxylic acids less acidic. While \(-\mathrm{Cl},-\mathrm{CN}\) and \(-\mathrm{NO}_{2}\) are electron withdrawing groups which increases the acidity of aromatic carboxylic acids.