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MHT CET · Chemistry · Amines

Which among the following reactions represents Carbylamines reaction?

  1. A \(\mathrm{R}-\mathrm{NH}_2+\mathrm{CHCl}_3+3 \mathrm{KOH} \underset{\text { alc }}{\stackrel{\Delta}{\longrightarrow}}\) \(\mathrm{R}-\mathrm{NC}+3 \mathrm{KCl}+3 \mathrm{H}_2 \mathrm{O}\)
  2. B \(\mathrm{R}-\mathrm{NH}_2+\mathrm{NHO}_2 \stackrel{\text { (i) } \mathrm{NaNO}_2+\mathrm{HCl}}{\longrightarrow}\) \(\mathrm{R}-\mathrm{OH}+\mathrm{N}_2 \uparrow+\mathrm{HCl}\)
  3. C \(\mathrm{R}-\mathrm{NH}_2+\mathrm{CH}_3 \mathrm{COCl} \stackrel{\text { pyridine }}{\longrightarrow}\)\(\mathrm{R}-\mathrm{NH}-\mathrm{COCH}_3+\mathrm{CHl}\)
  4. D \(\mathrm{R}-\mathrm{NH}_2+\mathrm{R}-\mathrm{X} \rightarrow \mathrm{R}_4 \stackrel{+}{\mathrm{N}} \overline{\mathrm{X}}+2 \mathrm{HX}\)
Verified Solution

Answer & Solution

Correct Answer

(A) \(\mathrm{R}-\mathrm{NH}_2+\mathrm{CHCl}_3+3 \mathrm{KOH} \underset{\text { alc }}{\stackrel{\Delta}{\longrightarrow}}\) \(\mathrm{R}-\mathrm{NC}+3 \mathrm{KCl}+3 \mathrm{H}_2 \mathrm{O}\)

Step-by-step Solution

Detailed explanation

\(\mathrm{R}-\mathrm{NH}_2+\mathrm{CHCl}_3+3 \mathrm{KOH} \underset{\text { alc }}{\stackrel{\Delta}{\longrightarrow}} \mathrm{R}-\mathrm{NC}~+\) \(3 \mathrm{KCl}+3 \mathrm{H}_2 \mathrm{O}\)
Carbylamine reaction