MHT CET · Chemistry · Haloalkanes and Haloarenes

When propene reacts with $H C l$ in presence of peroxide, the product is

A $1$ -chloro propane
B $1, 1$ -dichloro propane
C $2$ -chloro propane
D $1, 2$ -dichloro propane

Verified Solution

Answer & Solution

Correct Answer

(C) $2$ -chloro propane

Step-by-step Solution

Detailed explanation

When

H C l

reacts with an unsymmetrical alkene even in the presence of a peroxide, Markovnioff’s rule is followed.

Apply the relevant identity from the chapter and substitute the values established in the previous step, keeping the original constraint in view.

Use the simplified expression to isolate the unknown, then plug the result back into the question setup to confirm the working is internally consistent.

Cross-check against a boundary or limiting case. Both the dimensional balance and the qualitative behaviour at the extreme should agree with the candidate answer.

Combine the steps above to identify the correct option. The remaining choices each fail at least one of the consistency, dimensional, or boundary checks.

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When propene reacts with HCl in presence of peroxide, the product is

Step-by-step Solution

When propene reacts with $H C l$ in presence of peroxide, the product is